TTF羧酸配合物的合成與電化學性質.pdf

1、15r781400蠶訊犬碩士學位論文(2005屆)TTF羧酸配合物的合成與電化學性質SynthesisandElectrochemicalPropertiesofTTFCarboxylatesCoordinationCompounds研究生姓名苤壁塾指導教師姓名戴鯊f墼撞)專業名稱垂墊垡生研究方向整焦氆主：論文提交It螂2QQ生趟：TTF羧艘醚臺物豹會戰≮l擔純學性旗籀要ABS量RACTSincesubstantialapplicati

2、onshavebeenreportedinthefieldofmaterialscienceandsupramolecularchemistrytetrathiafulvalene(TTF)，includeditsderivatives，hasbeenoneofthemostextensivelystudiedmoleculesInthiswork，adicarboxylateofTFFwasusedforlhestudyandthem

3、ajorcontentsareasfollows：InintroductionthepropertiesandimportantachievementsofrrFderivativeswerereviewedbrieflythegeneralaspectofsupramolecularchemistryandthenewprogressinmolecularrecognitionweredescribed，andthedifferent

4、coordinationmodesofcarboxylgroupswerealsosummarizedInchapter2。theTITdicarboxylatesaltWasregardedas醵objectforresearchTheelectrochemicalresponsesofthesaltto小cationandthemechanismoftheequliblumshavebeendiscussedThiskindofmo

5、leculeshaspotentialapplicationsinredoxswitchandchemicalsensorInchapter3，anewsuDramolecularcompoundWaSobtainedbyreactionoftheTTFsodiumsaltwithbenzotriazoleItsXraycrystalstructurehaSbeendeterminedanditisformedbythecoordina

6、tionofcarboxylatewithNdionsandhydrogenbondsThebehaviors011molecularrecognitionhavealsobeenstudiedbYspectraandelectrochemistryInchapter4，twocoordinationcompoundswereobtainedbyreactionofligandwithnitratesoftransitionmetals

7、，Co(II)madNi(II)。Theircrystalstructuresandpropertiesweredetailedstudied，ThecarboxyloxygenatomsCaneithercoordinatedirectlytothemetalatomsorcombinebytheprotonsinthehexaaquometalcationsKeywords：Tetrathiafulvalene，Carboxylic